MATERIAL SAFETY DATA SHEET
Product Name: Osmium Tetroxide
Catalog Number: 20275, 20280
DOT Hazard Class: 6.1 (Toxic)
DOT Proper
Shipping Name: Osmium
Tetroxide
UN/NA ID No.: UN 2471
MSDS Updated: 9/16/05
Distributed By: Ladd Research
83 Holly Court
Williston, VT 05495
(802) 658-4961
HAZARDOUS
COMPONENTS
CAS Number Percent Exposure
Limits
Osmium tetroxide
20816-12-0 100% 0.002 mg/m³ (OSHA PEL)
0.002 mg/m³ (ACGIH TLV)
PHYSICAL AND
CHEMICAL DATA
Boiling Point: sublimes at 130EC
Specific Gravity:
4.91
Vapor Pressure: 11 mm Hg @ 27EC
Vapor Density: Not established
Melting Point: 40-42EC
(softens at 35EC)
Evaporation Rate:
Not established
Solubility in
Water: 5 g/100 ml (cold); 6
g/100 ml (hot)
Appearance and
Odor: Pale yellow
crystalline solid. Sharp chlorine-like
odor.
FIRE AND
EXPLOSION HAZARD DATA
Flash Point: Not applicable
Extinguishing
Media: Water spray or carbon
dioxide. DO NOT use organics
Special Fire
Fighting Procedures: Use
self-contained breathing apparatus with full face piece and full protective
clothing.
Unusual Fire and
Explosion Hazards: This
product is a strong oxidizer and may react explosively with many organic
compounds.
HEALTH HAZARD
DATA
Primary Routes of
Entry: Inhalation, skin,
ingestion
Inhalation: Coughing, shortness of breath,
unconsciousness. Could cause
tracheitis, bronchitis, bronchial spasm which may lead to inflammatory lesions
of the lung.
Skin: Dermatitis, possible skin discoloration
(green or black)
Ingestion: Irritation, cough, dyspnea, death
Eyes: Irritation, lacrimation, visual disturbance,
conjunctivitis, headache and corneal damage.
EMERGENCY AND
FIRST AID
Eye: Flush thoroughly with water. If discomfort occurs or persists, seek
medical assistance
Skin: Flush area with water and wash with soap and
water. If discomfort occurs or
persists, contact a physician.
Inhalation: Remove to fresh air. If breathing has stopped, perform artificial
respiration.
Ingestion: Give large amounts of water and induce
vomiting unless person is unconscious.
Seek medical attention immediately.
REACTIVITY
DATA
Stability: Stable
Incompatibility: Organic materials and hydrochloric acid
Hazardous
Decomposition Products: None
Hazardous
Decomposition: Will not
occur
SPILL,
DISPOSAL AND STORAGE INFORMATION
Spill: Sweep up or cover spill with dry sand or
vermiculite and mix well. Place in a
sealed container taking care to avoid dusting.
Disposal: Place in a sealed container and store in a
safe location until disposal by a qualified waste disposal company. Please consult local, state and federal
regulations before proceeding. (Please
Note: Spent osmium may be recovered and refined.)
Storage: Store away from light in tightly sealed glass
containers. Keep away from heat. Keep away from combustible materials.
PROTECTIVE
EQUIPMENT AND CONTROL MEASURES
Respiratory: Chemical cartridge respirator for acid gases.
Gloves: Rubber, neoprene
Eye: Full face mask
Ventilation: Local exhaust recommended. Use efficient fume hood.
SECTION 313
SUPPLIER NOTIFICATION
This chemical is
subject to the reporting requirements of Section 313 of SARA Title III.
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The information presented is believed to be correct and is the most accurate information available to us at this time. However, Ladd Research makes no warranty, express or implied, and assumes no liability for this information and the product described herein.