MATERIAL SAFETY DATA SHEET
Product Name: Sodium Hydroxide
Catalog Number:20315
DOT Hazard Class: 8 (Corrosive)
DOT Proper
Shipping Name: Sodium
Hydroxide, solid
UN/NA ID No.: UN1823
MSDS Updated: 9/16/05
Distributed By: Ladd Research
83 Holly Court
Williston, VT
05495
(802) 658-4961
HAZARDOUS
COMPONENTS
CAS Number Percent Exposure Limits
Sodium Hydroxide 1310-73-2
99-100% 2 mg/m³ (OSHA PEL)
2 mg/m³ (ACGIH TLV)
PHYSICAL AND
CHEMICAL DATA
Appearance and
Odor: Odorless, white,
deliquescent pellets
Solubility: 111 g/100 g of water
Specific Gravity:
2.13
pH: 13-14 (0.5% aqueous solution)
Boiling Point: 1390EC
Melting Point: 318EC
Vapor Density: >1 (air = 1)
FIRE AND
EXPLOSION HAZARD DATA
Fire: Not considered a fire hazard. Hot or molten material can react violently
with water.
Extinguishing
Media: Use any means
suitable for surrounding fire.
Special
Information: Wear full
protective clothing and NIOSH-approved self-contained breathing apparatus with
full facepiece operated in the pressure demand or other positive pressure mode.
HEALTH HAZARD
DATA
Inhalation: Severe irritant. Effects range from mild irritation to serious damage of the upper
respiratory tract. Symptoms may include
sneezing, sore throat or runny nose.
Severe pneumonitis may occur.
Ingestion: Corrosive.
May cause severe burns of mouth, throat and stomach. Severe scarring of tissue and death may
result. Symptoms may include bleeding,
vomiting, diarrhea, fall in blood pressure.
Damage may appear days after exposure.
Skin: Can cause irritation or severe burns.
Eye: Irritation with mild exposures or burns with
greater exposures.
EMERGENCY AND
FIRST AID
Inhalation: Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult,
give oxygen. Call a physician.
Ingestion: DO NOT INDUCE VOMITING! Give large quantities of water or milk if
available. Obtain medical attention
immediately.
Skin: Immediately flush skin with plenty water for
at least 15 minutes. Call a physician
if irritation persists.
Eye: Immediately flush eyes with plenty water for
at least 15 minutes, lifting lower and upper eyelids occasionally. Obtain medical attention immediately.
REACTIVITY
DATA
Stability: Stable under ordinary conditions.
Hazardous
Decomposition Products: Sodium
oxide. Decomposition by reaction with
certain metals releases flammable and explosive hydrogen gas.
Hazardous
Polymerization: Will not
occur.
Incompatibilities:
Contact with water, acids,
flammable liquids, and organic halogen compounds, especially trichloroethylene,
may cause fire or explosion. Contact
with nitromethane and similar nitro compounds causes formation of
shock-sensitive salts. Contact with
metals such as aluminum, tin and zinc causes formation of hydrogen gas.
SPILL,
DISPOSAL AND STORAGE INFORMATION
Spill: Ventilate area. Keep unnecessary people away.
Wear appropriate personal protective equipment. Pick up and place in a suitable container
for reclamation or disposal. Do not
flush caustic residues to the sewer.
Disposal: Should be handled as hazardous waste and sent
to a RCRA approved facility. State
andlocal disposal regulations may differ from federal disposal regulations.
Storage: Store in a tightly closed container. Store in a cool, dry, ventilated area away
from sources of heat, moisture and incompatibilities.
PROTECTIVE
EQUIPMENT AND CONTROL MEASURES
Ventilation: Local and/or general exhaust is
recommended.
Respirator: A half-face dust/mist respirator may be worn
for up to ten times the exposure limit.
A full-face piece dust/mist respirator may be worn up to 50 times the
exposure limit.
Skin: Impervious clothing, including boots, gloves,
lab coat, apron or coveralls, as appropriate.
Eye: Chemical safety goggles and/or a full face
shield.
SECTION 313
SUPPLIER NOTIFICATION
This chemical is
subject to the reporting requirements of SARA Title III.
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The information presented is believed to be correct and is the most accurate information available to us at this time. However, Ladd Research makes no warranty, express or implied, and assumes no liability for this information and the product described herein.